此反应由Meinwald在1963年首次报道,该反应为路易斯酸促进下的环氧化物转化为羰基化合物(酮或醛)的反应。除了路易斯酸,还发现质子酸也适合于这种重排。该反应通常是在无水条件以及当量或者过量的路易斯酸存在下,在惰性气氛保护下进行的。产物由环氧部分连接的取代基迁移性质、所用的溶剂和路易斯酸共同决定。
Meinwald, J.; Labana, S. S. and Chadha, M. S., J. Am. Chem. Soc.1963, 85, 582. DOI:10.1021/ja00888a022
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